<Superscript>57</Superscript>Fe Mössbauer spectroscopy,X-ray single-crystal diffractometry,and electronic structure calculations on natural alexandrite     

Sven-Ulf Weber  Michael Grodzicki  Werner Lottermoser  Günther J. Redhammer  Gerold Tippelt  Johann Ponahlo  Georg Amthauer 《Physics and Chemistry of Minerals》2007,34(7):507-515

Natural alexandrite Al₂BeO₄:Cr from Malyshevo near Terem Tschanka, Sverdlovsk, Ural, Russia, has been characterized by ⁵⁷Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine oxidation state and location of iron. The sample contains 0.3 wt% of total iron oxide. The ⁵⁷Fe Mössbauer spectrum can be resolved into three doublets. Two of them with hyperfine parameters typical for octahedrally coordinated high-spin Fe³⁺ and Fe²⁺, respectively, are assigned to iron substituting for Al in the octahedral M2-site. The third doublet is attributed to Fe³⁺ in hematite. Electronic structure calculations in the local spin density approximation are in reasonable agreement with experimental data provided that expansion and/or distortion of the coordination octahedra are presumed upon iron substitution. The calculated hyperfine parameters of Fe³⁺ are almost identical for the M1 and M2 positions, but the calculated ligand-field splitting is by far too large for high-spin Fe³⁺ on M1.  相似文献   

Past and future polar amplification of climate change: climate model intercomparisons and ice-core constraints   总被引：1，自引：0，他引：1  

V. Masson-Delmotte  M. Kageyama  P. Braconnot  S. Charbit  G. Krinner  C. Ritz  E. Guilyardi  J. Jouzel  A. Abe-Ouchi  M. Crucifix  R. M. Gladstone  C. D. Hewitt  A. Kitoh  A. N. LeGrande  O. Marti  U. Merkel  T. Motoi  R. Ohgaito  B. Otto-Bliesner  W. R. Peltier  I. Ross  P. J. Valdes  G. Vettoretti  S. L. Weber  F. Wolk  Y. Yu 《Climate Dynamics》2006,27(4):437-440

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Holocene record of productivity in the NW Iberian continental shelf     

V. Alves Martins  C. Patinha  E. Ferreira da Silva  J.-M. Jouanneau  O. Weber  F. Rocha   《Journal of Geochemical Exploration》2006,88(1-3):408

A multiproxy approach (textural characteristics, heavy metal concentrations and benthic foraminifera data) was adopted to study the OMEX core KSGX 40, collected at the Galicia Mud Deposit (NW Iberian outer continental shelf) and recording the last ca. 4.8 ka cal BP. Geochemical profiles of Fe, Mn, Zn, Co, Cr, Cu, Ni, Pb, Al and Ca show significant temporal variations. Benthic foraminifera productivity proxy suggests that the recorded muddy events were contemporaneous of a higher C_org flux to the marine benthic environment. The higher flux of organic matter, following a long-term intensification of the upwelling and coinciding with a finer sedimentation, led to depressed levels of oxygen beneath the water-sediments interface and to early diagenetic processes of several redox-sensitive elements.  相似文献   

Remarks on the Definition and Estimation of Friction Velocity   总被引：3，自引：1，他引：2  

Rudolf O. Weber 《Boundary-Layer Meteorology》1999,93(2):197-209

One of the mainscaling parameters in similarity theory of the atmospheric boundary layer is friction velocity. Unfortunately, several definitions of friction velocity exist in the literature. Some authors use the component of the horizontal Reynolds stress vector in the direction of the mean wind vector to define friction velocity. Others define the friction velocity by means of the absolute value of the horizontal Reynolds stress vector. The two definitions coincide only if the direction of the mean wind vector is parallel to the horizontal Reynolds stress vector. In general, the second definition gives larger values for the friction velocity. Over complex terrain the situation is further complicated by the fact that the terrain following flow is not necessarily horizontal. Thus, several authors have proposed to use terrain following coordinate systems for the definition of friction velocity. By means of a large dataset of fast-response wind measurements with an ultrasonic anemometer the friction velocities resulting from the different definitions are compared. Furthermore, it is shown that friction velocity can be well estimated from horizontal wind speed, and even better from simple horizontal or vertical turbulence parameters.  相似文献   

The behavior of total lightning activity in severe Florida thunderstorms     

Earle Williams  Bob Boldi  Anne Matlin  Mark Weber  Steve Hodanish  Dave Sharp  Steve Goodman  Ravi Raghavan  Dennis Buechler 《Atmospheric Research》1999,51(3-4)

The development of a new observational system called LISDAD (Lightning Imaging Sensor Demonstration and Display) has enabled a study of severe weather in central Florida. The total flash rates for storms verified to be severe are found to exceed 60 fpm, with some values reaching 500 fpm. Similar to earlier results for thunderstorm microbursts, the peak flash rate precedes the severe weather at the ground by 5–20 min. A distinguishing feature of severe storms is the presence of lightning ‘jumps' — abrupt increases in flash rate in advance of the maximum rate for the storm. The systematic total lightning precursor to severe weather of all kinds — wind, hail, tornadoes — is interpreted in terms of the updraft that sows the seeds aloft for severe weather at the surface and simultaneously stimulates the ice microphysics that drives the intracloud lightning activity.  相似文献   

Coupling an ocean wave model to an atmospheric general circulation model     

Susanne L Weber  Hans von Storch  Pedro Viterbo  Liana Zambresky 《Climate Dynamics》1993,9(2):63-69

A coupled model, consisting of an ocean wave model and an atmospheric general circulation model (AGCM), is integrated under permanent July conditions. The wave model is forced by the AGCM wind stress, whereas the wind waves modify the AGCM surface fluxes of momentum, sensible and latent heat. We investigate the following aspects of the coupled model: how realistic are the wave fields, how strong is the coupling, and how sensitive is the atmospheric circulation to the spatially and temporally varying wave field. The wave climatology of the coupled model compares favorably with observational data. The interaction between the two models is largest (although weak) in the storm track in the Southern Hemisphere. Young windsea, which is associated with enhanced surface fluxes is generated mostly in the equatorward frontal area of an individual cyclone. However, the enhancement of the surface fluxes is too small to significantly modify the climatological mean atmospheric circulation.This paper was presented at the Second International Conference on Modelling of Global Climate Variability, held in Hamburg 7–11 September 1992 under the auspices of the Max Planck Institute for Meteorology. Guest Editor for these papers is L. Dümenil  相似文献   

Receiver function arrays: a reflection seismic approach   总被引：6，自引：0，他引：6  

T. Ryberg  & M. Weber 《Geophysical Journal International》2000,141(1):1-11

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Acoustic simulation of P-wave propagation in a heterogeneous spherical earth: numerical method and application to precursor waves to PKPdf     

Ch. Thomas  H. Igel  M. Weber  & F. Scherbaum 《Geophysical Journal International》2000,141(2):307-320

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上部地壳的流体作用与大理岩的低温塑性   总被引：5，自引：0，他引：5  

刘俊来 Weber  K 《岩石学报》2000,16(4):499-505

本文应用光学显微镜、透射电子显微镜和阴极发光显微镜系统研究了Ｗａｔｅｒｂｅｒｇ断层带（纳米比亚）内粗晶大理岩中发育的构造岩,宏观碎裂结构与微观糜棱装结构是断层构造岩的主要特点。巨大的孪形碎屑与弥漫的细小粒质形成了鲜明的反差,广泛发育的压溶颖合线与多阶段方解石细脉遍布构造带不同部位,ＴＥＭ亚微粒粒度具有简单的峰值分布（～０．３～０．４μｍ）,但动态重结晶颗粒的粒度却具有较大的变化范围（０．１～３．０  相似文献   

Imaging the Dead Sea Transform with scattered seismic waves   总被引：2，自引：0，他引：2  

N. Maercklin  C. Haberland  T. Ryberg  M. Weber  Y. Bartov  the DESERT Group 《Geophysical Journal International》2004,158(1):179-186

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